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Do the secondary bottles for Rescue® have to be opaque?

No, they do not. Rescue® contains ingredients that help to prevent the hydrogen peroxide's reaction with exposure to air or light.

Rescue® Disinfectants are based on a patented technology called Accelerated Hydrogen Peroxide® (AHP®). This technology contains stabilizing agents that prevent the hydrogen peroxide from reacting to exposure to air or light, meaning that Rescue never has to be stored in an opaque bottle to protect it's stability and efficacy.

You may also find these resources useful:

Video: What is AHP®? What are the Ingredients in Rescue™